"Test tube" reactions for negative ions

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Carbonates (CO32-) react with dilute acids to form carbon dioxide.

CO32- + 2H+ → CO2 + H2O

Carbon dioxide turns limewater milky.

Halide ions (chloride, Cl-, bromide, Br-, iodide, I-) in solution produce precipitates with silver nitrate solution in the presence of dilute nitric acid.

eg NaCl(aq) + AgNO3(aq) → AgCl(s) + NaNO3(aq)

Silver chloride is white

Silver bromide is cream

Silver iodide is yellow.

Sulfate ions (SO42-) in solution produce a white precipitate with barium chloride solution in the presence of dilute hydrochloric acid. Ba2+(aq) + SO42-(aq) → BaSO4(s)

Nitrate ions (NO3-)are reduced by aluminium powder in the presence of sodium hydroxide solution to form ammonia.

Copper carbonate (CuCO3) decomposes to copper oxide when heated (green to black).

Zinc carbonate (ZnCO3) decomposes to zinc oxide when heated (white to white (but hot zinc oxide is yellow)).

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